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Found one definition

  1.                 From The Collaborative International Dictionary of English v.0.48:
                    

    Hoof \Hoof\, v. i. 1. To walk as cattle. [R.] --William Scott. [1913 Webster]

    2. To be on a tramp; to foot. [Slang, U.S.] [1913 Webster]

    To hoof it, to foot it.

    On the hoof, of cattle, standing (on the hoof); not slaughtered.

    beef on the hoof, live cattle. [Webster 1913 Suppl.]